Search results for "Kraft process"
showing 10 items of 44 documents
Combustion Properties of Birch (Betula pendula) Black Liquors From Sulfur-Free Pulping
2016
Sulfur-free pulping has an environmental advantage over the traditional kraft process. This article describes the combustion properties of the black liquors produced from silver birch (Betula pendula) sawdust using three different cooking processes: two sulfur-free cooks (soda-anthraquinone and oxygen-alkali), and one reference kraft cook. It also considers the corresponding black liquors from an integrated forest biorefinery, in which a hot-water pretreatment of feedstock was performed prior to pulping. With the same cooking time, the total burning times for the sulfur-free black liquors were higher (15–55%) than those for the conventional kraft black liquors. However, no significant diffe…
Role of lignin and sodium carbonate on the swelling behavior of black liquor droplets during combustion
2018
AbstractA partial removal of lignin from black liquor (BL) by carbonation and lignin precipitation was studied. In lignin-lean BL droplets during combustion in a laboratory furnace at 800°C in stagnant air, the maximum swelling was decreased. This observation was interpreted as showing that the lignin content decrement is due mainly to removal of higher molar mass (HMM) lignin and that the Na2CO3content of the BL is increased. Stepwise precipitation experiments with industrial softwood and hardwood kraft BLs by carbonation (resulting in pH decrement from 13 to 9) indicated that a fraction of HMM lignin (MM >10 kDa) with a higher amount of carbohydrates precipitated more prominently and e…
Green geopolymeric concrete using grits for applications in construction
2018
Abstract This work investigates the production a green geopolymer-based concrete for a sustainable construction material using biomass wastes from a kraft pulp industry: fly ash (as main alumina-silicate source) and grits (as aggregate). Moreover, a simple, reproducible, ambient temperature, and low-cost manufacture is followed. Mix design aims to maximize wastes incorporation and optimize the mechanical performance. Preliminary tests indicate that the used wastes may be successfully employed to produce green geopolymeric concretes with satisfying mechanical performance (up to 18 MPa), according to the European standards. Furthermore, they represent a viable solution to reduce the environme…
Description of kraft cooking and oxygen–alkali delignification of bamboo by pulp and dissolving material analysis
2008
Abstract The oxygen delignification of two bamboo ( Bambusa procera ) kraft pulps with kappa numbers of 13.6 and 20.0 were studied under typical conditions. Based on detailed analysis data on both the kraft and oxygen-delignified pulps and the corresponding spent liquors (black liquors and oxygen stage effluents), three yield and four selectivity estimation methods, utilizing component material balances, were tested resulting in the value ranges 96.2–97.9% and 43.5–60.4%, respectively, for oxygen delignification process studied. The traditional selectivity using the viscosity and kappa number relation was 66.9–68.4%. The studied bamboo kraft pulps behaved typically as birch kraft pulps duri…
Delignification of bamboo (Bambusa procera acher)
2004
Abstract Delignification of bamboo ( Bambusa procera acher ) was carried out by conventional kraft and soda pulping under varying conditions to determine the relationships between selected cooking parameters (EA 14–20%, sulfidity 0–45%, maximum temperature 165 and 170 °C, and time at maximum temperature 30–95 min) and pulp properties (kappa number, viscosity, and yield). Results indicated that in order to obtain relatively low kappa numbers (17–24), high sulfidity (35–45%) at lower EA (14–16%) increased both pulp viscosity and yield compared to the case of low sulfidity (0–15%) at higher EA (16–18%). Pulp with lower kappa numbers (11–15) and acceptable viscosities (1080–1190 ml/g) can be ob…
Gas chromatographic and mass spectrometric analysis of chlorinated catechols occurring in pulp bleach liquors
1982
Chlorination step (C-step), spent bleach liquor from a kraft pulp mill and the product from the chlorination of guaiacol in aqueous solution have been investigated for their content of chlorinated catechols. After separation the samples were derivatized with diazoethane and analysed by glass capillary gas chromatography with an electron capture detector. The external standard mixture of all ethylated chlorocatechols was used in the measurements. The structures of the compounds identified were confirmed by gas chromatography/mass spectrometry. Eight chlorinated catechols were identified from a sample prepared by chlorination of guaiacol with Cl2 in aqueous solution. However, only four of the…
High-Performance Liquid Chromatographic Study on Oxidation Products of Lignin and Humic Substances
1991
We describe a convenient method of preparing samples and characterizing the mixture of degradation products obtained from alkaline cupric oxide oxidation of water samples containing lignin and humic substances. The method was applied to one unpolluted humic water sample and a total mill effluent of a kraft pulp mill. The fractions (Mr > 1000) obtained by ultrafi1tration were oxidized and the products (mixtures of degradation products) were analyzed by reversed-phase high-performance liquid chromatography (Spherisorb 5 ODS column). Acetonitrile-0.01 M phosphate buffer (pH 2) was used as the eluent in a gradient system and UV (set at 280 nm) as the detection system. Differences in the …
Chlorophenanthrenes, alkylchlorophenanthrenes and alkylchloronaphthalenes in kraft pulp mill products and discharges
1994
Abstract Chlorinated phenanthrenes (PCPHs; P=1–5), alkylphenanthrenes (C4-PCPHs; P=1–3), dimethylnaphthalenes (C2-PCNs; P=1–4) and trimethylnaphthalenes (C3-PCNs; P=1–2) were analyzed by high resolution gas chromatography/high resolution mass spectrometry (HRGC/HRMS) in pulp, effluent and biosludge of two kraft pulp mills (mills 1 and 2). These compounds were indicated to be formed in the manufacture of both bleached hardwood and softwood kraft pulp. Different compound groups dominated in mill 1 samples compared to mill 2 samples. Differences between birch and pine pulp from mill 1 were observed for all substance groups but in mill 2 pulp only for PCPHs. The highest concentrations of PCPHs …
Free and bound chlorophenols in kraft pulp bleaching effluents
1992
Abstract Free (F; hexane extractable) and chemically bound (B; alkali extractable) chlorophenols, catechols and guaiacols were measured from effluents of the C and E stages of chlorobleaching of kraft softwood pulp. Ratio B/F was in moste cases nearly one, but for tetrachloroguaiacol B/F was 20 in C and 2.70 in E stage. Organically bound chlorine (OCl) in chlorophenols was less than one percent of the total AOX (Adsorbable Organic Halogen) emitted.
Microwave-assisted catalytic esterification of α-glucoisosaccharino-1,4-lactone with tall oil fatty acids
2016
Background: Carbohydrates-rich materials are partly degraded during alkaline kraft pulping into a complex mixture of aliphatic carboxylic acids consisting of α-glucoisosaccharinic acid as one of the main acids. On the other hand, crude tall oil, containing significant amounts fatty acids, is obtained as a by-product from kraft pulping. One interesting novel approach is to utilize chemically both these side-streams by producing renewable surfactants from aliphatic carboxylic acids and fatty acids via esterification. Results: In this paper, lauric (C12:0) and oleic (C18:1) acids as well as a mixture of tall oil fatty acids were esterified with α-glucoisosaccharino-1,4-lactone in a microwave-a…